• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    Disclosed is a solid state compressor for electrochemically compressing a fluid, comprising: a stack of compressor cells, comprising at least one compressor cell having a membrane-electrode assembly sandwiched between two cell plates, an enclosure, securing the stack of compressor cells on its opposite sides, and at least one contact body, interposed between the stack of compressor cells and the enclosure and in contact with an outer surface of the stack of compressor cells, in which space is contained between the enclosure and the contact body, which space is configured to contain hydraulic fluid under pressure. The invention further relates to a method of operating such a solid state compressor.
    公开号:BE1027327B1
    申请号:E20195816
    申请日:2019-11-21
    公开日:2021-04-19
    发明作者:Albert Bos；Rombout Adriaan Swanborn
    申请人:Hyet Holding B V；
    IPC主号:
    专利说明:

    Solid State Compressor and Method for Providing Back Pressure on a Stack of Solid State Compressor Cells The present invention relates to a solid state compressor for electrochemical compression of a fluid. The invention further relates to an enclosure for a solid state compressor and a pressure adjustment mechanism for use in a solid state compressor. The invention further relates to a method of operating a solid state compressor according to the invention.
    While conventional mechanical compressors use mechanical means such as pistons or rotors for compressing a fluid, solid state compressors rely on the electrochemical transport of said fluid through a membrane using an ion transport mechanism. In order to compress the working fluid in an electrochemical manner, a solid-state compressor typically comprises a compressor cell which is made up of one or more stacked membrane-electrode assemblies (also known as MEA, assembly ”). The MEA's electrodes are connected to a power supply to maintain an electrical potential difference between the electrodes. This potential difference is necessary to electrochemically displace the ionized working fluid across the proton exchange membrane (commonly known as PEM) against the pressure gradient that exists across the membrane. The direction of the electric current thus determines the direction of ion transport, in which the low pressure working fluid is ionized at the positively charged anode and is recombined with the separated electrons on the high pressure cathode side of the MEA.
    The electrochemical hydrogen compressor is a commonly known solid state compressor, in which hydrogen is supplied to the compressor cell and oxidized into protons and electrons. The protons are then entrained through the membrane and the electrons are transferred by an external circuit, after which the protons and electrons are reduced to molecular hydrogen. In this process, hydrogen moves against a pressure gradient from an area of low pressure to an area of high pressure, resulting in an increase in pressure across the membrane. Compression of other working fluids, such as water or ammonia, is also possible. Solid state compressors have a number of significant advantages over mechanical compressors. This is because solid state compressors have no moving parts and are generally compact in design. In addition, solid state compressors make it possible to compress fluids at very high pressures, up to 1000 bars and more, with operating efficiencies greater than those of mechanical compressors.
    Another advantage of electrochemical compression is that it makes it possible to purify the working fluid, since the membrane only allows the ionized working fluid to be transported.
    During the process of compressing the working fluid, there are very high pressure differences on the different sides of the compressor cell. To maintain these pressure differences and obtain sufficient sealing of the compressor cell, a sufficiently large back pressure must be exerted on the compressor cell. To do this, the compressor cell is usually secured between two flanges held together by a series of - bolts which engage the flanges near their peripheral edges.
    A disadvantage of this fixing structure is that due to the high pressures in the compressor cell, the compressor cell exerts an evenly distributed gas pressure force on the flanges. As a result, the flanges will tend to curve in their center, away from the point of engagement of the set of bolts that hold the flanges together. This results in poor electrical contact in the central part of the compressor cell or even rupture of the internals of the cell.
    Another problem with the fixing structure described above is caused by the contraction and expansion of the compressor cell due to the thermal and pressure effects that occur during the electrochemical compression of the working fluid, which causes variation the sealing and contact pressure between the compressor cell and the respective flanges. Due to this pressure variation and the continuous movement of the compressor cell during expansion and contraction, bolt assemblies gradually loosen over time.
    This causes leaks and requires regular inspection and retightening of the bolt assemblies.
    The object of the present invention is to provide a solution for at least one of the drawbacks mentioned above.
    The present invention provides a solid state compressor for electrochemically compressing a fluid, comprising: a stack of compressor cells, comprising at least one compressor cell having a membrane-electrode assembly sandwiched between two cell plates, an enclosure, securing the stack of compressor cells on its opposite sides, and at least one contact body, interposed between the stack of compressor cells and the enclosure and in contact with an outer surface of the stack of compressor cells, in which space is contained between the enclosure and the contact body, which space is configured to contain pressurized hydraulic fluid.
    Solid state compressor can be hydrogen compressor
    - electrochemical, but can also be configured to compress other working fluids such as water or ammonia.
    The principle of operation of these solid state compressors is the same, i.e. they compress the working fluid by allowing the working fluid to pass through a membrane-electrode assembly which is part of a cell. compressor.
    The compressor cell can thus form part of a stack of compressor cells comprising several compressor cells.
    Each of the compressor cells therefore comprises a membrane-electrode assembly which is fixed between two cell plates, in which the cell plates serve to separate and support the various membrane-electrode assemblies as well as to supply the working fluid to the cell. membrane-electrode assembly and guide the working fluid away from it.
    However, the invention does not explicitly relate to an electrolyser or any other similar apparatus for changing Hz0 to Hz and O.
    The apparatus according to the invention is an apparatus for receiving Hz with low pressure and for delivering Hz with high pressure.
    The stack of compressor cells includes an exterior surface that faces away from the at least one membrane-electrode assembly contained therein. In order to compensate for internal pressures in the stack of compressor cells during operation of the solid state compressor, the enclosure which secures the stack of cells is configured to exert a back pressure on the stack of cells at least equal. and generally greater than this internal pressure in the stack of compressor cells. Said back pressure is thus exerted on the outer surface of the stack of compressor cells by means of an interface entity in the form of a contact body. The contact body is in contact, and in particular in full contact, with the outer surface of the stack of compressor cells, which outer surface is in a common case formed by an outermost cell plate of the stack of compressor cells. cells. This allows the contact body to efficiently transmit the forces exerted by the stack of compressor cells on the enclosure and vice versa.
    Since a space is contained between the enclosure and the contact body, the back pressure provided by the enclosure is however not exerted directly on the contact body. Instead, pressurized hydraulic fluid is contained in the aforementioned space and is thus interposed between the enclosure and the contact body. The forces exerted by the enclosure on the stack of compressor cells are thus transmitted both by the contact body and by the hydraulic fluid. A major advantage of this construction is that uniform contact and pressure distribution on the contact body and therefore on (the outer surface of) the stack of compressor cells is achieved at all times. Even though the enclosure itself can bend or deform under the high pressures prevailing in the stack of compressor cells, the compressor, according to the present invention, is capable, thanks to the space containing the pressurized hydraulic fluid. , to maintain an evenly distributed / distributed back pressure on the contact body and the stack of compressor cells. This thus solves the problem of poor electrical contact in the central part of the stack of compressor cells and the possible rupture of the internals of the cell.
    An additional advantage of allowing the enclosure to exert the necessary back pressure on the stack of compressor cells via the contact body and the pressurized hydraulic fluid is that in the event that the back pressure on the compressor the cell stack exceeds the internal pressure of the compressor cell stack, the progressive loosening of the connections between the different parts of the enclosure which push the enclosure together, allowing the enclosure to compress the cell stack, has no immediate effect on the integrity of the cell stack. In the case of a direct connection between the cell stack and the enclosure, loosening of the connections and subsequent relative displacement of the different parts of the enclosure will result in loss of contact between the enclosure and the cell stack. compressor, causing the cell stack to leak. The pressurized hydraulic fluid will however maintain uniform contact with the contact body at the sole cost of a slight decrease in hydraulic pressure in the event that the connections between the different parts of the enclosure loosen to the point of causing some displacement. parts of the enclosure, thus increasing the volume of the space to a small extent. In an advantageous embodiment of the solid state compressor according to the present invention, the solid state compressor comprises a pressure adjustment mechanism configured to adjust or regulate the pressure of the hydraulic fluid contained in the space. However, it is also possible for the space between the enclosure and the contact body to be fixed in volume and for a fixed quantity of pressurized hydraulic fluid to be contained in said space.
    In this case, the hydraulic fluid is pressurized to a fixed pressure. This pressure must, however, aim to compensate for the highest possible internal pressure of the stack of compressor cells. The compressor, including the cell stack and enclosure, must therefore constantly withstand pressures equal to or greater than the highest possible internal pressure for which the compressor cell stack is designed. The possibility of adjusting the pressure of the hydraulic fluid contained in the space between the enclosure and the contact body makes it possible to choose back pressures greater than the current operating pressure inside the cell block and therefore to ensure the necessary waterproofing. However, these back pressures can now be chosen lower than the highest possible internal pressure of the compressor cell stack because the hydraulic fluid pressure and therefore the back pressure can be increased with increasing pressure of. operation of the stack of cells.
    The pressure adjustment mechanism can be configured to adjust the pressure of the hydraulic fluid based on the pressure on a cathode side of at least one membrane-electrode assembly. The cathode side of the membrane-electrode assembly is the side where the working fluid is compressed. An increase in the internal pressure of the cell stack such as that prevailing on the cathode side will in most cases require a higher hydraulic fluid pressure to provide the necessary back pressure and thus ensure proper sealing of the cell stack. compressor. In the case where the pressure of the hydraulic fluid is controlled on the basis of a pressure prevailing on the cathode side of at least one membrane-electrode assembly, it can be ensured that the back pressure supplied by the pressurized hydraulic fluid is automatically equal to or greater than the internal pressure of the cell stack.
    To further ensure the tightness and integrity of the stack of compressor cells, the pressure adjustment mechanism may be configured to maintain a fixed ratio between the pressure prevailing on the cathode side of the at least one membrane-electrode assembly. and hydraulic fluid pressure. It is therefore preferable that the pressure of the hydraulic fluid is higher, preferably between 1.5 times and 2.5 times higher, and more preferably 2 times higher than the pressure prevailing on the cathode side of the at least one membrane assembly. - electrodes. A dynamic control of the hydrostatic pressure inside the space contained between the enclosure and the contact body is thus obtained.
    In another embodiment of the solid state compressor according to the invention, the space contained between the enclosure and the contact body is hydraulically connected to a hydraulic fluid reservoir. The reservoir effectively increases the total volume of hydraulic fluid which acts to provide back pressure on the contact body and simultaneously on the outer surface of the compressor cell stack. In the event of a hydraulic fluid leak where part of the hydraulic fluid escapes, increasing the volume of hydraulic fluid will ensure a decrease in pressure drop. It is therefore less likely that a hydraulic fluid leak will immediately cause the pressure to drop to a level below that of the internal pressure of the cell stack. In addition, the presence of a hydraulic fluid reservoir provides access to the hydraulic fluid contained in the reservoir and to the space contained between the enclosure and the contact body, away from the stack of cells. compressor itself.
    As a possible means of adjusting the hydraulic fluid pressure in space, the combination of the contact body and the stack of compressor cells can be movably connected to the enclosure so that it is movable relative to each other. to the enclosure. In this way, the space contained between the enclosure and the contact body can be changed in volume, which allows the pressure in the hydraulic fluid to be adjusted. In the event that the space is hydraulically connected to a hydraulic fluid reservoir, the hydraulic fluid reservoir may alternatively or additionally have a variable volume in order to change the total volume of the closed system comprising the hydraulically connected space and the reservoir. of hydraulic fluid, thereby adjusting the degree of compression of the hydraulic fluid and therefore the amount of back pressure exerted on the stack of compressor cells. The pressure adjustment mechanism can thus be configured to adjust the volume of the aforementioned hydraulic fluid reservoir.
    To adjust the volume of the hydraulic fluid reservoir, the pressure adjustment mechanism may include a displacement piston, including a first piston head surface in contact with the hydraulic fluid reservoir, to change the volume of the hydraulic fluid reservoir. when moving the piston head. The displacement piston is typically contained in a housing, the housing encircling the piston head in a fluid tight manner. The housing connects to or merges into a wall of the hydraulic fluid reservoir, such that the first piston head interfaces with the hydraulic fluid. When the displacement piston is moved inwardly towards the hydraulic fluid reservoir, the volume of the hydraulic fluid reservoir is effectively reduced, the hydraulic fluid contained therein being further compressed. When the displacement piston is moved outward from the hydraulic fluid reservoir, the volume of the hydraulic fluid reservoir is effectively increased, the hydraulic fluid it contains then being less compressed.
    The displacement piston may also include a second piston head surface opposite the first piston head surface, which second piston head surface contacts a reservoir of pressurized fluid to change the volume of the fluid reservoir under. pressure when moving the piston head. Much like the first piston head, the second piston head may be contained in a housing, the housing encircling the piston head in a fluid-tight manner and mating with or merging into a wall, in this case of the fluid reservoir. under pressure. When the displacement piston is moved inwardly towards the pressurized fluid reservoir, the volume of the pressurized fluid reservoir is effectively reduced, the pressurized fluid contained therein being more compressed. As the displacement piston is moved outward from the pressurized fluid reservoir, the volume of the pressurized fluid reservoir is increased with the pressurized fluid contained therein being compressed to a lesser extent. Since the first and second piston heads are part of the same piston, inward movement of the first piston head will result in outward movement of the second piston head and vice versa. With this simultaneous movement of the piston heads, the volumes of the reservoirs are adjusted in dependence on one another, which makes it possible to balance the pressures prevailing in the hydraulic fluid reservoir and in the pressurized fluid reservoir.
    It is particularly advantageous that the cathode side of at least one membrane-electrode assembly is connected to the pressurized fluid reservoir, whereby the fluid in the pressurized fluid reservoir is under the same pressure as the working fluid. compressed on the cathode side of the membrane- - electrode assembly. In one possible embodiment, the connection between the cathode side of the membrane-electrode assembly and the pressurized fluid reservoir is a fluidic connection, in which the fluid in the pressurized fluid reservoir is in fact the same as the working fluid pressurized by the solid state compressor. The advantage of such a fluidic connection between the cathode side of the membrane-electrode assembly and the pressurized fluid reservoir is that the pressure of the hydraulic fluid and therefore the back pressure on the stack of compressor cells is automatically adjusted according to the internal pressure of the cell stack.
    With the fluidic bond, a change in pressure on the cathode side of the membrane-electrode assembly causes a similar change in fluid pressure in the pressurized fluid reservoir. Since the two opposing but reliably movable displacement piston heads of the displacement piston are in contact with the hydraulic fluid reservoir and the pressurized fluid reservoir, respectively, the change in pressure in the pressurized fluid reservoir will cause the displacement of the pressure fluid reservoir. displacement piston, thereby changing the pressure in the hydraulic fluid reservoir simultaneously. Since the space contained between the enclosure and the contact body is hydraulically connected to a hydraulic fluid reservoir, the hydraulic fluid pressure contained in the space will also change, which will influence the amount of back pressure exerted on it. stacking of compressor cells via the contact body.
    In order to achieve a fixed pressure ratio between the pressures in the hydraulic fluid reservoir and the pressurized fluid reservoir, the surface areas of the first piston head surface and the second piston head surface may differ. one from the other. In particular, the ratio between the surface areas of the first piston head surface and the second piston head surface which are in contact with the hydraulic fluid and the pressurized fluid determines the ratio of the pressures prevailing in the pressure reservoir. hydraulic fluid and the pressurized fluid reservoir. In other words, the forces applied to the piston heads perpendicular to their surfaces at the interface with the pressurized fluids are equal to the pressure multiplied by their surface areas. By choosing the surface areas of the first piston head surface and the second piston head surface as a function of the desired pressure difference between the hydraulic fluid reservoir and the pressurized fluid reservoir, the relative back pressure exerted on the stack of compression cells can thus be controlled automatically and dynamically.
    In yet another embodiment of the solid state compressor according to the invention, the solid state compressor comprises two contact bodies, each interposed between the enclosure and a different side of two opposite sides of the stack of compressor cells. , wherein a space is contained between the enclosure and the respective contact bodies, which spaces are configured to contain pressurized hydraulic fluid.
    An advantage of this embodiment is that the hydraulic fluid contained in the two spaces enables uniform contact and pressure distribution to be obtained on the contact bodies.
    The pressure of the hydraulic fluid contained in either of these spaces can be adjusted by a pressure adjustment mechanism according to one of the embodiments described above.
    In order to create a self-balancing system, the contact bodies may be movably embedded within the enclosure such that the volume of the spaces between the enclosure and the respective contact bodies change upon movement of the enclosure. contact body with respect to the enclosure.
    As the contact bodies contact opposite sides of the compressor cell stack, the cell stack will move along with the contact bodies.
    This movement of the combination of contact bodies and
    —The stacking of cells inside the enclosure makes it possible to balance the pressures of the hydraulic fluid respectively contained in each of the spaces.
    In the event that the pressure of the hydraulic fluid in one of the spaces is changed, for example by means of a pressure adjustment mechanism as described in one of the previously discussed embodiments, the contact bodies and
    - the stack of cells move inside the enclosure, thus modifying the volume of the spaces and equalizing the pressures prevailing in each of the spaces.
    As another means of creating a self-balancing system, the spaces between the enclosure and the contact bodies can be hydraulically connected to each other.
    In this way, the pressure in each of the spaces will also be kept equal.
    In a particular embodiment, the enclosure may comprise two opposing and interconnected flanges which respectively hook around each of the contact bodies, thus entirely encircling a surface of said contact bodies opposite to the surface in contact with an outer surface of the stack of compressor cells. An advantage of the total encirclement of this surface of the contact bodies is that no direct contact is established between the enclosure (the flanges) and the surfaces of the contact bodies on which the compressive forces are exerted. Instead, the surfaces are fully in contact with the hydraulic fluid, ensuring an even distribution or distribution of pressure thereon. In a common case, the flanges grip around each of the contact bodies far enough to allow the contact bodies to move relative to the flanges while maintaining a fluid seal between the flanges and the contact bodies. It is possible that the opposing flanges are interconnected by a pre-tensioned connection, which pushes the opposing flanges towards each other so that the hydraulic fluid contained in the spaces is compressed. By compressing the hydraulic fluid, the connection simultaneously introduces a compressive preload into the stack of attached compressor cells. The preload is generally chosen to be equal to or greater than the highest possible pressure under which the stack of compressor cells is designed to operate.
    Opposing flanges can be joined together by one or more bolted joints. In order to counteract the effects of creep and loosening of bolt assemblies, which results in a loss of the initial preload of bolt assemblies, one or more Belleville washers may be placed between at least one of the flanges and a bolt head or nut. the bolted assembly. The invention also relates to an assembly of an enclosure and at least one contact body for a solid state compressor according to the invention. The invention further relates to a pressure adjustment mechanism for adjusting the pressure in a hydraulic fluid contained in a space contained between an enclosure and a contact body of a solid state compressor according to the invention. The specifics as well as the advantages of the assembly and of the pressure adjustment mechanism are already described in detail in relation to the various possible embodiments of the solid state compressor according to the invention.
    Finally, the invention relates to a method of operating a solid state compressor according to the invention, comprising the introduction of a pressurized hydraulic fluid into the space between the enclosure and the contact body.
    The method may further include adjusting the pressure in the hydraulic fluid.
    The pressure in the hydraulic fluid can thus be adjusted as a function of the pressure prevailing on a cathode side of the at least one membrane-electrode assembly.
    It is possible to maintain a fixed ratio between the pressure prevailing on the cathode side of the membrane-electrode assembly and the pressure of the hydraulic fluid.
    The pressure in the hydraulic fluid can in this case be maintained higher, preferably between 1.1 times and 2.5 times higher, and more preferably twice higher than the pressure prevailing on the cathode side of the at least one. membrane-electrode assembly.
    The specifics as well as the advantages of one or the other of these methods for the operation of a solid state compressor are already described in detail with regard to the different possible embodiments of the solid state compressor according to the invention. invention.
    In order to further elucidate the invention, embodiments will be described by way of nonlimiting examples with reference to the figures, among which: FIG. 1 shows a perspective view of a solid state compressor according to the invention, FIG. Figure 2 shows an exploded view of the solid state compressor of Figure 1, and Figure 3 shows a schematic sectional view of a solid state compressor according to the invention.
    The figures show specific exemplary embodiments of the invention and should not be construed as limiting the invention in any way or form.
    Throughout the description and figures, corresponding reference numerals are used for corresponding elements.
    Figures 1 and 2 respectively show a perspective view and an exploded view of a solid state compressor 1 according to the invention.
    The solid state compressor 1 comprises a stack of compressor cells 2 comprising multiple membrane-electrode assemblies 3 sandwiched between cell plates 4. The outermost plates 5 of each cell stack 2 are generally formed by plates. current collectors to serve as a passage for electrically connecting the electrodes to a power source. The compressor cell stack 2 is, on opposite sides, secured between an enclosure 6 which maintains pressure on the cell stack 2. The illustrated housing 6 includes two flanges 7 which are interconnected near their peripheral edges by a set of bolted joints formed by bolts 8 and nuts 9. Between the opposite outer surfaces 10 of the stack of cells 2 and the enclosure 6 are interposed two contact bodies 11 which are in contact with said outer surfaces 10. As as can be seen in FIG. 3, explained below, a space is contained between each of the flanges 7 and the contact bodies 11, which space contains a hydraulic fluid under pressure. In order to supply hydraulic fluid or to retract hydraulic fluid from this space, the contact bodies 11 are provided on their sides with openings for supplying hydraulic fluid 12. FIG. 3 shows a schematic sectional view of a solid state compressor according to the invention. Here too, a stack of compressor cells 21 is illustrated, of which two opposing outer surfaces 22 are fixed between two contact bodies 23. The combination of the stack of cells 21 and the contact bodies 23 is contained in an enclosure 24. , comprising two opposing flanges interconnected by means of bolted joints 26. The flanges 25 thus surround each of the contact bodies 23, completely encircling the surfaces of the contact bodies opposite to the surfaces in contact with the outer surfaces 22 of the stack. cells 21. Between the flanges 25 and the contact bodies 23, spaces 27 are contained, which contain a pressurized hydraulic fluid.
    28. Seals 29 are provided between the sides of the flanges 25 and the contact bodies 23 in order to obtain a closed volume capable of containing the hydraulic fluid under pressure 28. The upper space of the spaces 27 is hydraulically connected to a reservoir. of hydraulic fluid 30 by means of a hydraulic fluid line 31. The lower space of the spaces 27 is in this illustrated embodiment of the solid state compressor which is neither hydraulically connected to a hydraulic fluid reservoir, nor connected. hydraulically to the upper space. Thus, a passive pressure compensation system is obtained on the lower side of the solid state compressor 20. The last mentioned variations are however within the scope of the invention.
    The volume of the hydraulic fluid reservoir 30 is variable by a pressure adjustment mechanism 32 including a displacement piston 33. The displacement piston 33 is movable within the piston housing 34 and has a first head surface. piston 35 which is in direct contact with hydraulic fluid 28 contained in hydraulic fluid reservoir 30. The displacement piston further includes a second piston head surface 36 opposite to the first piston head surface 35, which second piston head surface 36 is in direct contact with a pressurized fluid 37 contained in a pressurized fluid reservoir 38. Since the first and second piston head surfaces 35, 36 are part of the same piston, they effect a simultaneous movement, thereby balancing the pressures in the pressurized fluid reservoir and in the hydraulic fluid reservoir 30,38. The ratio between the pressures in the two reservoirs therefore depends on the surface areas of the piston head surfaces 35, 36. The pressurized fluid reservoir 38 is connected to the cathode side of the membrane-electrode assemblies contained in the stack of cells 21. by a pressurized fluid line 39. The pressurized fluid 37 contained in the pressurized fluid reservoir 38 is therefore the same as the working fluid of the compressor 20.
    权利要求:
    Claims (25)
    [1]
    1. Solid state compressor for electrochemically compressing a fluid, comprising: - a stack of compressor cells, comprising at least one compressor cell having a membrane-electrode assembly sandwiched between two cell plates, - an enclosure, fixing the compressor cell. 'stack of compressor cells on its opposite sides, and - at least one contact body, interposed between the stack of compressor cells and the enclosure and in contact with an outer surface of the stack of compressor cells, in which space is contained between the enclosure and the contact body, which space is configured to contain pressurized hydraulic fluid.
    [2]
    2. A solid state compressor according to claim 1, wherein the solid state compressor comprises a pressure adjustment mechanism configured to adjust the pressure of the hydraulic fluid contained in the space.
    [3]
    A solid state compressor according to claim 2 and wherein the pressure adjustment mechanism is configured to adjust the hydraulic fluid pressure based on a pressure prevailing on a cathode side of the at least one membrane-electrode assembly.
    [4]
    4. A solid state compressor according to claim 3 wherein the pressure adjustment mechanism is configured to maintain a fixed ratio between the pressure on the cathode side of the at least one membrane-electrode assembly and the pressure of the hydraulic fluid.
    [5]
    5. A solid state compressor according to claim 4, wherein the hydraulic fluid pressure is greater, preferably between 1.1 times and 2.5 times greater, and more preferably 2 times greater than the pressure prevailing on the. cathode side of at least one membrane-electrode assembly.
    [6]
    6. A solid state compressor according to any one of claims 1-5 wherein the space is hydraulically connected to a reservoir of hydraulic fluid.
    [7]
    7. A solid-state compressor according to claim 6 and any one of claims 2-5, wherein the reservoir has a variable volume, wherein the pressure adjustment mechanism is configured to adjust the volume of the hydraulic fluid reservoir.
    [8]
    8 A solid state compressor according to claim 7, wherein the pressure adjustment mechanism comprises a displacement piston, including a first piston head surface in contact with the hydraulic fluid reservoir, for changing the volume of the reservoir. hydraulic fluid when moving the piston head.
    [9]
    A solid state compressor according to claim 8, wherein the displacement piston comprises a second piston head surface opposite the first piston head surface, which second piston head surface is in contact with a reservoir of fluid. pressurized to change the volume of the pressurized fluid reservoir as the piston head moves.
    [10]
    10. A solid state compressor according to claim 9, and wherein the cathode side of the at least one membrane-electrode assembly is connected to the pressurized fluid reservoir.
    [11]
    A solid state compressor according to claim 9 or 10, wherein the surface areas of the first piston head surfaces and the second piston head surfaces are different from each other.
    [12]
    12. A solid state compressor according to any one of the preceding claims, and in which the solid state compressor comprises two contact bodies, each being interposed between the enclosure and a different side from among two opposite sides of the stack of cells. compressor, wherein a space is contained between the enclosure and the respective contact bodies, which spaces are configured to contain pressurized hydraulic fluid.
    [13]
    13. A solid state compressor according to claim 12, and wherein the contact bodies are movably embedded within the enclosure such that the volume of the spaces between the enclosure and the respective contact bodies change. during a movement of the contact bodies relative to the enclosure.
    [14]
    14. A solid state compressor according to claim 13, wherein the spaces between the enclosure and the respective contact bodies are hydraulically connected to each other.
    [15]
    15. - A solid state compressor according to any one of claims 12-14, wherein the enclosure comprises two opposite and interconnected flanges which respectively hook around each of the contact bodies, thus entirely encircling a surface of said body. contact opposite to the surface in contact with an exterior surface of the stack of compressor cells.
    [16]
    16. A solid state compressor according to claim 15, wherein the opposing flanges are mutually connected through a tension prestressed connection, which prestress pushes the opposite flanges towards each other so that the hydraulic fluid. contained in the spaces is compressed.
    [17]
    17. A solid state compressor according to claim 15 or 16, wherein the opposing flanges are interconnected by at least one bolted assembly.
    [18]
    18. A solid state compressor according to claim 17, and wherein one or more Belleville washers are positioned between at least one of the flanges and a bolt head or nut of the bolt assembly.
    [19]
    19. An assembly of an enclosure and at least one contact body for a solid state compressor according to any one of the preceding claims.
    [20]
    20. A pressure adjustment mechanism for adjusting the pressure of a hydraulic fluid contained in a space contained between an enclosure and a contact body of a solid state compressor according to any one of claims 1 to 18.
    [21]
    21. A method for operating a solid state compressor according to any one of claims 1 to 7, comprising introducing a pressurized hydraulic fluid into the space between the enclosure and the contact body.
    [22]
    22. The method of operating a solid state compressor according to claim 21, and wherein the method further comprises adjusting the pressure in the hydraulic fluid.
    [23]
    23. The method of operating a solid state compressor according to claim 22, and wherein the pressure in the hydraulic fluid is adjusted based on the pressure on a cathode side of the at least one membrane-electrode assembly.
    [24]
    24. The method of operating a solid state compressor according to claim 22, and wherein a fixed ratio is maintained between the pressure on the cathode side of the at least one membrane-electrode assembly and the pressure in the hydraulic fluid.
    [25]
    25. A method for operating a solid state compressor according to claim 24, and wherein the pressure in the hydraulic fluid is maintained greater, preferably between 1.1 times and 2.5 times greater, and more preferably 2 times. greater than the pressure on the cathode side of the at least one membrane-electrode assembly.
    类似技术:
    公开号 | 公开日 | 专利标题
    FR2957361A1|2011-09-16|HIGH TEMPERATURE | ELECTROLYSIS WITH ENHANCED OPERATING SAFETY
    BE1027327B1|2021-04-19|SOLID STATE COMPRESSOR AND METHOD FOR PROVIDING BACK PRESSURE ON A STACK OF SOLID STATE COMPRESSOR CELLS
    EP1522112A2|2005-04-13|Basic cell for fuel cell with helical structure, production method thereof and fuel cell comprising numerous basic cells
    FR2865853A1|2005-08-05|Fuel cell for motor vehicle, has longitudinal traction devices to provide traction for support plates, and having coil springs disposed between support plates for absorbing longitudinal dilatation of basic cells
    EP3012892B1|2017-07-19|Electrochemical device with stack
    BE1027333A1|2021-01-06|Solid state electrochemical compressor
    BE1027326B1|2021-04-08|Flow field plate and compressor comprising such a plate
    WO2014207388A1|2014-12-31|Device for the electrochemical purification and compression of hydrogen having a plurality of stages
    EP2294647B1|2012-04-04|Delivery head for a fuel cell
    EP2909883B1|2016-07-20|Improved fuel cell
    JP4010193B2|2007-11-21|High pressure hydrogen production equipment
    EP3476977B1|2020-05-13|Reversible repeating unit of water electrolysis or co electrolysis | or fuel cell | functioning under pressure and decoupled compressive stress
    FR3073323A1|2019-05-10|ELECTROCHEMICAL ACCUMULATOR WITH SPECIFIC BIPOLAR ARCHITECTURE
    FR2686738A1|1993-07-30|ELECTRICAL ACCUMULATOR WITH TWO ELEMENTS.
    EP2729983A1|2014-05-14|Power connection and tightening clamp for a fuel cell module, and associated fuel cell system
    EP2669981B1|2016-05-04|Compact electric current generator comprising a fuel cell and an integrated hydrogen source
    WO2013007583A1|2013-01-17|Device for storing dioxygen and/or dihydrogen, and related fuel cell system
    FR3097377A1|2020-12-18|PEMFC fuel cell
    WO2021014104A1|2021-01-28|Polymer electrolyte membrane fuel cell
    CA3063286A1|2018-11-22|Reactor | for electrolysis or co-electrolysis of water or fuel cell | operating in a pressurized operating mode and comprising a clamping system suitable for such an ope rating mode
    WO2015118257A1|2015-08-13|Lightweight stack of membrane/electrode assemblies
    FR2969393A1|2012-06-22|Method for inerting fuel cell electrically connected to electric load, involves injecting inert fluid into cathodic conduit of cell of fuel cell, and injecting reducer fluid into anodic conduit of cell
    同族专利:
    公开号 | 公开日
    KR20210096158A|2021-08-04|
    WO2020106153A1|2020-05-28|
    EP3884081A1|2021-09-29|
    JP2022509167A|2022-01-20|
    CN113302339A|2021-08-24|
    FR3088938A1|2020-05-29|
    SG11202105392QA|2021-06-29|
    BE1027327A1|2021-01-06|
    CA3120274A1|2020-05-28|
    NL2022067B1|2020-06-05|
    US20220018031A1|2022-01-20|
    AU2019384465A1|2021-06-17|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    WO2001025700A1|1999-10-01|2001-04-12|Maget Henri J R|Electrochemical refrigeration system and method|
    JP2007023343A|2005-07-19|2007-02-01|Honda Motor Co Ltd|Apparatus for producing high-pressure hydrogen|
    US20100078317A1|2008-09-30|2010-04-01|General Electric Company|Pressurized electrolysis stack with thermal expansion capability|
    US20120217156A1|2011-02-28|2012-08-30|Honda Motor Co., Ltd.|High-pressure hydrogen producing apparatus|
    US20130039779A1|2011-08-08|2013-02-14|Xergy Inc.|Electrochemical motive device|
    US20150001067A1|2012-01-18|2015-01-01|H-Tec Systems Gmbh|Electrolyzer|
    DE102012018243A1|2012-09-17|2014-03-20|Propuls Gmbh|Method and system for operating an electrolyzer|
    EP3868708A1|2020-02-21|2021-08-25|L 2 Consultancy B.V.|Method and system for direct thermal decomposition of a hydrocarbon compound into carbon and hydrogen|
    法律状态:
    2021-05-31| FG| Patent granted|Effective date: 20210419 |
    优先权:
    申请号 | 申请日 | 专利标题
    NL2022067A|NL2022067B1|2018-11-23|2018-11-23|Solid-state compressor and method for providing counter pressure on a solid-state compressor cell stack|
    [返回顶部]